Luck of the draw somtimes you get male and females all up to chance
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CHIMCHAR
Chimchar can learn the move Blaze Kick from breeding. Simply breed a male Hitmonlee or Blaziken that knows Blaze Kick with a female Chimchar. The resulting Chimchar that hatches from the egg should now have Blaze Kick as one of it's moves.
Good/Answer 2:You can breed a Chimchar and hope its female, or do trading at GTS in Jubilife. :3Answer 1:you cant chimchars are only male
To get a Chimchar with blaze kick, you would have to breed your female Chimchar with a male Blaziken/Hitmonlee/Lucario/Smergle that already knows blaze kick. The easiest ones would be Blaziken and Hitmonlee since they learn blaze kick while leveling.
Pick Piplup or Chimchar and then trade for a piplup or chimchar