You must choose chimchar as your starter.
If your starter is male, then you must reset the game many time and try again, until it's female.
ATTENTION: Every starter (inklusive Eevee and other non-starters) is about 87,5% male and 12,5% female. It's rare to get a female starter.
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You must breed a Monferno or Infernape with a Pokemon to get the chimchar egg.
You can get a Chimchar if you trade it from games Diamond, Pearl, and Platinum.
Chimchar
The starter pokemon for Diamond and Pearl are Turtwig, Piplup, and Chimchar.
trade from pearl, diamond, or platnium