You insert Pokemon leaf green go to route 201 or 202 and use the poke radar
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A total of three Pokemon evolve using the Fire Stone: Vulpix, Eevee, and Growlithe.
vulpix is not in Pokemon platinum version.
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.
Use a fire stone on Vulpix.
Vulpix can be found in the area outside of Mt. Pyre.