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Just as the Umbreon, upgrade an Eevee during Daytime and make sure it's happy with you. (Feed it loads of Vitamins and berries and what not), and a other way without needing Vitamins or berries is to make it hold a Soothe Bell and level it up during the day!

TIP: All you need to do is upgrade while it likes you 1 level, and it's sure to evolve to Espeon.

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Q: How do you get a Espeon in Pokemon Diamond?
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Can Espeon and Umbreon mate in Pokemon Diamond?

Yes. All eevees can matewith all other eevees in diamond, pearl, and platinum.


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