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A Pokémon does not obey you if it is a) traded from another game or b) carelessly hacked and you don't have the Gym Badge that makes Pokémon of its level obey. This goes for Mew as well.
After getting the eighth gym badge, all pokémon will obey you, with the exception of Mew. The only way to make Mew obey you fully would be to use the 'Box 1 Slot 1' Mew cheat on Gameshark/Action Replay. -------------------------------------------------------------------------------------------------------- I have a Gameshark and the Box 1 Slot 1 cheat copies the pokemon in question but will NOT make Mew obey. If you have a Gameshark find a version of emerald and warp to Faraway island. Catch Mew, trade mew, copy mew. Now you have many mews and they obey.
I think if you have all badges, and beat the elite four he should obey you. I'm sorry, but you'll have to be an excellent Pokemon hacker if you want Deoxys and Mew to obey you.
try giving it a soothe bell or get more badges, because if u get certain badges the Pokemon up to a certain level will obey u
Mew can be migrated from Pokemon Emerald if that game was participated in the Japanese Mew event to get the Old Sea Map or have 999 Pokemon in Pokemon Ranch and Hailey will give you Mew.