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Eevee cannot be found in pokemon black or white, and must be traded to be obtained.
by painting it black i don't know
It cannot be caught in Pokemon white but can be transferred from a generation IV game.You aren't able to catch a wild Eevee in pokemon white or black, you have to trade it from a different pokemon game with Eevee as a catchable pokemon. Hope that helped :)
Nowhere , you see, Eevee is not in the new one where black and white takes place. Eevee is in the Kanto region so it's not in Black and White.
Espeon (the purple Eevee) is obtained by maximizing Eevee's friendship during the day;Umbreon (the black Eevee) is obtained by maximizing frienship during the night.