Pinsir is a rare pokemon found in the Safari Zone and since it's rare it doesn't appear that often. An easier method to obtaining the pokemon is via the Game Corner Exchange in Celadon City it's a bit pricey but collecting the coins is faster than finding the pokemon.
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No only leafgreen can.
The Resort Area
Firered and leafgreen both can catch different Pokemon but there pokedex is the same, here is some examples: magmar only in leafgreen not firered, oddish in firered not leafgreen, ekans in firered not leafgreen, bellsprout in leafgreen not firered, pinsir in leafgreen not firered.
You can get over 151 pokemons. Your starter off Pokemon will/could be Bulbasaur, Squirtle, or Charmander.
Pinsir does not have an evolution