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To evolve an Electabuzz into an Electivire, attach an Electrizer to the Electabuzz and then trade with someone else that owns a copy of Diamond/Pearl/Platinum and then Electabuzz will evolve into an Electivire!Right here there are some questions awaiting your answers...http://wiki.answers.com/Q/FAQ/2085
No, Electabuzz can't evolve in Pokemon FireRed version. However, Electabuzz has a pre-evolution, Elekid, which can only be obtained through breeding.
You have to trade Electabuzz to someone while he/she is holding an Electrizer.
If you have an electrizer you can use it to evolve electabuzz by letting electabuzz hold it and then trade it.
He doesn't evolve at a level. You need to have the item electrizer, give it to electabuzz, and trade it. Then it will evolve into electivire.