It can evolve anytime after it learns the attack "Rollout".
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Lickitung will evolve into Lickilicky in Pokemon: Diamond, Pearl, Platinum, HeartGold, SoulSilver, Black, & White after any level-up after it learns the move: Rollout.* *Lickitung learns the move, Rollout, naturally when it reaches level: 33
Likitung will evolve into Likiliky after it learns the move AncientPower. In Pokemon Diamond, Pearl, and Platinum, that is at level 33. It may be different for Soul Silver and Heart Gold.
To catch lickitung you have to talk to dawns sister and if your lucky she mite say lickitung. It worked for me and I have breeded and made 28 lickitung s and I mite make a event to sell lickitung in pearl
To get Lickitung in Pokemon Pearl you need the National Pokedex which you get for seeing every Pokemon in the Sinnoh Pokdex. After getting the National Pokedex talk to your rival's sister in Sandgem Town until she says Lickitung have started appearing in Acuity Lackfront. Go to Acuity Lakefront and a Lickitung should eventually appear.
If this is a generation three or earlier game, then Lickitung doesn't evolve, and you can't get Lickilicki (The evolved form of Lickitung). This is because Lickilicki is a generation four Pokemon and didn't exist at the time Fire Red and Leaf Green were released, because they are generation three. If you want to know about Diamond, Pearl, Platinum, HeartGold or SoulSilver, then Lickitung evolves while leveled up and knows rollout. Lickitung learns rollout at level 30, so when yours reaches that point, let it learn rollout, and then raise it another level. It will evolve into Lickilicki.