I caught a Relicanth last night completely by surprise.
I was Surfing at the top of the water on Route 226 (above the guys who teaches you the elemental hyper beams) and i faced a rock (leaving enough water in front of me to fish) and started fishing with a Super Rod.
I was looking for a Seadra but came across Relicanth so i caught it. (Still looking for the Seadra haha)
Hope that helps!
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You can catch it when you use dive.
You find relicanth underwater near sootopolis city.
neither of them is better, they are both the same, but in diamond, you catch dialga, and in pearl, you catch palkia, and you can catch different Pokemon in each game for example: you can catch this Pokemon in diamond, but not pearl but: you can catch this different Pokemon in pearl, but not diamond
You can catch makuhita in the fighting area in Pokemon diamond
How do you get a cherrim in Pokemon diamond.