You can catch it when you use dive.
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erwater cavern surrounding sootopolis city
no you cant if you want relicanth you have to beat seven gyms teach dive to one of your Pokemon and search through underwater grass it may take a while
They're a rare Pokemon you can find underwater just outside of Sootopolis. Other than in Ruby, Sapphire and Emerald, you cannot obtain them.
You find relicanth underwater near sootopolis city.
no you can get a relicanth at the bottom of the sea