i catch them with poke'balls,ultra balls,time balls,premeir balls,all kinds,but that's me....................
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To catch a mightyena get a level.20 0r .15 Pokemon and catch poocheyena then give it exp. share go to the lilycove city and go left and there you will see trainers defeat them you get it to lv. 20 and there!you have that Pokemon.
yes you just have to level it up again
There is no place where you can catch a level 100 pokemon unless you use some cheat device. (Such as an action replay)
you have to either catch a legendary or raise a Pokemon
Victory Road has fairly high level Pokemon in it