take as many pics as it takes poke'mon you havent done yet. you might have to go to different places.
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no... you can't get the actual Pokemon. There is a Pokemon sign, though. In the cave level, when you're next to victreebell, turn around and take a picture of the constellation thingy.
It is Altering Cave which you can enter only after you beat the Pokemon league.
beat the Pokemon league
Get the national dex and beat the elite 4.
Check youtube for some videos