you find it in the wild in johto region
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Entei is roaming Johto after you encounter it at Burned Tower.
entei is a roming Pokemon of Johto. to catch it u have to chase it. if u run or use your bike it will run somewhere else. it is similar to catching Mesprit in Pokemon Diamond,pearl,or platinum.
you cant catch entei on Pokemon pearl. entei is a johto Pokemon and Pokemon pearl is a sinnoh game. the only way to getentei is to trade it over from another game games compatible are Pokemon diamond, Pokemon platinum, Pokemon soulsilver and Pokemon heartgold. the last two i am sure you can get entei. (i have seen it in the wild)
master ball. but save it if you want it to use it on entei or raioku which run in the wild
No you cannot catch Entei in Pokemon Emerald.