thers a fisherman in fushia city, talk 2 him say yes and he gives u a good rod
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Psyduck is in firered not leafgreen you can find it using a good or super rod in the safari zone.
You can get one by fishing in Vermilion City. It is somewhat rare and you need the Super Rod to be able to get it :)Use a good rod.
You get it at the house on the right of the safari zone wardens house in fuchsia city.
good rod or super rod next to bills house.You can also catch a Poliwhirl there.Poliwag is not in leafgreen you get horsea instead via the good rod and super rod. To get poliwag trade one from firered.
just magikarp.