You have a 1 in 8,192 chance of any Ninetales you find being shiny. There is no way (other than AR/GS cheats) to increase those chances.
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ninetails does not evolve but if you ment vulpix use firestone
To evolve Ninetales in the game Ruby Destiny Life of Guardians, you have to use a fire stone. He is evolved from Vulpix and has nine tails and a shiny gold fleece.
Vulpix evolves into Ninetails. In order to get a Ninetails you need to use a fire stone on Vulpix.
Vulpix, it evolves into Ninetails.
You give your Vulpix a fire stone and it will evolve into Ninetails