Luxray can only learn Ice Fang from breeding. To get a Luxray that knows Ice Fang you need to breed a female Shinx with a male Piloswine that knows Ice Fang. The resulting egg will be a Shinx that knows Ice Fang upon hatching.
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It can through breeding...
move tutor route 212 pastoria side
luxray learns thunder fang at lvl 42 That is what happened to my luxray but on pokemondb.net, it says that luxray learns thunder fang at lvl 35.
no luxray cannot learn the move thunderpunch but he can learn the move thunder fang
A Glaceon with Ice Fang.