Once Charizard has reached level 60 go to Two Island and go north you will find a house go inside and speak to the lady and make sure Charizard is the first pokemon on your list she will notice it and say she will teach it the most powerful fire attack blast burn allow her to do so and now your Charizard will have the move.
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The Blast burn TM i am not sure if they even made a TM but if you have a charizard in Pokemon firered or leafgreen go to the woman at one two or maybe three island its cape brink is where she is learn blast burn from her and trade charizard to your Pokemon emerald. There is no blast burn TM in generation III as far as I am aware of, but I do not believe that there is any way to get blast burn, frenzy plant, or hydro cannon in emerald. Sorry. (unless of course you get it in firered/leafgreen, and trade it over) ~zeusfireair [I'm pretty sure that the move tutor for those three moves is on two island]
talk to that old hag on 2 island at the top of it and have your charizard with you and she'll say your Pokemon sucks let me teach it blast burn
It must be tutored by a special tutor.
No, Arcanine cannot learn Blast Burn because it is not a starter Pokemon. Infernape, Charizard, and other fire type starters can learn blast burn.
to let blaziken to learn blast burn is trade it for a charizard then you need to catch a latias (this is only for sapphire) then level it up to level 100 then after that put charizard at first in your party then summary it then their will be a bad egg at your party after it hatches you have to turn it off (this is not true ) this is the truth hatch it with a charizard who knows blast burn.