Mythic Stone is found in the 3rd. mine. Here are the floor numbers
From floor 0 to 255, every floor that ends in 0. From floor 255 to 999, every floor that ends in 5.
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The Third Mine. You can only find Mythic Stone after you get all the Cursed Tools and have all of those turned into Blessed Tools.
You need a mythic hammer
On Harvest Moon: DS and Harvest Moon: DS Cute, you get the third mine by reaching the bottom of the second mine, which is 255 floors deep.
once you unlock the first mine on the 6th floor there will be that ore in the rocks just smash it with your hammer
255 floors