Find a Pokemon that has serious nature, then walk up to this "guy" and if it asks you if you want to show him a Pokemon with a serious nature then click yes and choose the Pokemon you caught.
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you talk to this guy in a city or win lucky number show
theres a guy who gives you 5 of them if you show him a certain pokemon. hes thenews reporter guy in solaceon town. they dont start selling them until after the 7th or 8th badge.
At the very end of route 25, there is a house and a guy asks you to see certain Pokemon, show him the Pokemon and he gives you different stones, one of which is a water stone! hope this helps!~
you beat the giant onix and show a guy a pikachu lv 42 and a electrod and you will get a shiny voltrob
no you don't give pokemon