Yes he does, at level 54.
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Flamethrower could only be learned by leveling up until Generation 3, when it became TM35.
Flareon can be a Male but it can also be a Female.Flareon can be either male or female, depending on the gender the Eevee it evolves from has. With a few exceptions, such as legendary Pokemon, every Pokemon can be either male or female as of Pokemon Gold and Silver (Red, Blue, and Yellow didn't have genders).
Naturally? No. By HM? Yes.
You can evolve Eevee by giving it:A thunder stone evolves it into: JolteonA water stone evolves it into: VaporeonA fire stone evolves it into: Flareon
Articuno is not able to learn the move Sky Attack. It can only be taught Sky Attack with the TM 43 in Pokemon Red and Blue. Sky Attack is no longer TM 46 in later games so it's impossible for Articuno to learn Sky Attack outside of Pokemon Red and Blue.