No, Exp Share only works while the Pokémon is in your party.
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yes there are 2 Pokemon day care centers 1 in cerulean city for leveling up your Pokemon & the 2nd day care center is on island 4 this is the main day care where you can make baby Pokemon..VERONICA
The Day Care in Pokemon Ruby is on the route West of Mauville City.
You put Empoleon and Ditto to the Pokemon Day Care and wait for a long time. Then go back to Pokemon Day Care talk to the old man.
If you left two Pokemon that are of different genders and are of the same egg group, you can get an egg from the Day Care Man outside of the Day Care after you've left the Pokemon there for a while.
you can put ditto with a Pokemon in the day care. or two Pokemon of opposite gender. doesn't work with non gender Pokemon like lugia or porygon.