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Riolu first has to evolve into Lucario in order to learn Aura Sphere. However, if you own Pokemon Ranger: Shadows of Almia you can download a special mission called Rescue the Kidnapped Riolu through wifi. After you complete the mission you are able to transfer a special Riolu that knows Aura Sphere to Pokemon Diamond, Pearl, or Platinum versions.

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Q: Does Riolu Learn Aura Sphere at any level in Platinum?
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