No they appear randomly
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At the end of the game, new Pokemon appear in the trophy garden. one hint. max repels and a pokeradar.
Trophy Garden (Talk to Mr. Backlot), Route 209, Route 210 (South) their are VERY RARE so you might want to use the Pokeradar. And it might take a Day or 2
The Trophy Garden is behind the Pokemon Mansion in Sinnoh. Several Pokemon can only be found there. Pokemon able to be caught in the garden include: Pichu, Pikachu, Staravia, Roselia, and Kricketune. Afer talking to Mr. Backlot, special Pokemon appear in the garden including: Clefairy, Jigglypuff, Meowth, Chansey, Ditto, Eevee, Porygon, Cleffa, Igglybuff, Marrill, Azurill, Plusle, Minun, Castform, Bonsly, Mime Jr., and Happiny.
you go to the trophy garden behind the Pokemon mansion.
In the trophy garden its a daily Pokemon :D