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In Pokémon Emerald version I believe you have the option to fight and catch Rayqauza before the Pokémon League. In Pokémon Ruby and Sapphire Version you can only encounter and catch Rayquaza after you have defeated the Pokémon League.
it is in the Pokemon league where you use waterfall
Yes, if playing White Version.
fish at the poke' league waterfall using the super rod
Pokeman here, to catch a Steelix you have to evole a Onix or beat the Pokemon league and go to the temple in snowpoint city and catch one. Wow! that was quick! You can catch them at Victory Road and the deepest parts of Iron Island too.