no
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I don't believe you can use the PS3 Guitar Hero controller on the PC to play anything
Im not sure about XP, but I'm running Vista and all I did was plug in the dongle, let windows install its own drivers and away you go playing GH3 on the PC with PS3 guitar.
The PS3 will not play PC games and PC game Mods will not mod a PS3 game.
yes just plug it in the microphone port
No PS3 games are not the same as a PC game with the same title