You can get Ursaring in Pokémon Emerald in the safari zone. You can also evolve it from Teddiursa or trade for it.
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NEED TO TRADE FROM EMERALD
Ursaring is a Johto pokemon unavailable in Firered you will only see certain trainers use it but you cannot actually capture one. Only Emerald can obtain a Teddiursa which will evolve to Ursaring when leveled up enough and if that doesn't work out for you the only other game that gets one is Pokemon XD Gale of Darkness.
Tediursa evolves at lv 30 into ursaring
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Ursaring normally appears in victory road, and in the first part of the cave in mount silver.