yes you can by putting infernape and ditto in Pokemon daycare center
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You can get a Chimchar if you trade it from games Diamond, Pearl, and Platinum.
in the begining of the game the profeser will give you three Pokemon and you have to pick one the three Pokemon are chimchar,piplup and turtwig.
Poketransfer from Pearl Diamond or Platinum
Turtwig Chimchar Piplup
...shiny Pokemon are always shiny... ._.