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No. However, you can obtain it in Pokemon Black/White. Coming soon to America, you can obtain a special Celebi in Heartgold/Soulsilver. Transfer it to you Black or White Version (coming March 6) and you'll trigger a special event. Ahem, this Celebi is going to be released through Wi-Fi Distribution. Keep an eye on Pokemon.com for new information.
No, Zorua and Zoruaork are Generation V Pokemon, and as such will be available in the next games.

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Q: Can you catch zorua in Pokemon HeartGold?
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