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It's possible, but it's harder to catch them. So I suggest using the master ball. Another thing you might ry is before using any other pokeball, weaken them to the red and put them to sleep or any other status effect. Then try throwing a pokeball other than the master ball. Hope this helps you.

nvrmnd don't use the master ball if you have any try to catch it with a lvl. ball i did

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Q: Can you catch lugia or Ho-oh without a master ball?
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