propabaly not seeing as most emulators play gamnes as a singular console with no connection. you MAY be able to use netplay like wifi but i am not sure as i have not got experience with a ds emulator; i have with similer older emulators though
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You have to migrate the pokemon so any pokemon you have in your leafgreen can be in pal park but it disappears from your leafgreen
You import a Charizard and a Ditto from any game via Pal Park, then breed them together for an egg. It will be a Charmander.
You can obtain any Pokémon you have captured on the Emerald cart, but you need to go to the pal park to release and re-capture them.
Never in any Pokemon game can you catch a starter but hold on if you migrate a blastoise and charizard from firered or leafgreen to soul silver and then go to the pal park you can catch it.
You will be able to catch ANY Pokemon you have migrated from GBA, legendaries you name it! ...unless they were hacked I suppose.