no but if you do the cheat move_objects on you can delete the parents.
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if you want any sims to move out, then all you have to to do is get the news paper and click on "find own place" then you choose who want to go and they will leave.
Have them look in the paper or on the computer and select "find own place".
There isn't a Church in The Sims 2, however you can make your own as a community lot. In the related link below it shows you how.
You can buy them at the supermarket, or, if you have a watermellon or watermellon seeds, you can plant your own.
No you can't start your own buisness you can only have a job on sims 3 you can't start your buisness.