Yes, in B/W2, you can tutor it. But I would suggest this moveset: Brick Break, Aerial Ace (Fight Weakness), Night Slash(obviously), and ice punch(Good STAB). EV train ATTACK!.
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Yes, you need to use the Move Tutor.
Magmar learns thunderpunch by egg move.
You Need A Male Smeargle To Use Sketch On A Pokemon That Uses Pursuit And Then Use Sketch On Another Pokemon That Uses Ice Punch. When You have Done That Breed The Smeargle With a Female Weavile/Sneasel And Wa La You Have A Weavile That Knows Ice Punch And Pursuit But You Need The National Dex To Catch Smeargle Without It You Cant Make Weavile Learn Them 2 Moves Because It Impossible
Yes, Thunderpunch is a special attack in the game. Thunderpunch didn't become a physical attack until Diamond/Pearl/Platinum, which introduced the physical/special split.
at the start