Somewhere between Level 30 and 45. There is no point in Grudge.
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to evolve eevee into sylveon, you need to level it up with maximum two affection hearts on pokemon - amie plus it has to learn a fairy type move. your best best is level it up to level 29, as it would learn charm, which asof gen VI is a fairy type move
Sky uppercut is the final move that Combusken learns. It will learn to do this move at level 59.
Yes, if you use a rare candy to level it up to a level where it learns a move, it will still prompt you to learn the move.
Level 13
Psybeam is not a TM move. It's learn-able by level up by Butterfree, Venonat, Venomoth, Kadabra, Alakazam, Mr. Mime, Porygon, Espeon, Misdreavus, Girafarig, Remoraid, Octillery, and Porygon2. It's also usable by Pokemon that know Metronome if it's chosen by that move.