Mt. Moon(I think)/Team Rocket hideout/Pokemon tower/Saffron city/two island/Victory road.
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You can't buy rare candy in fire red. You can find them all over the region though.
Rare Candies are scattered all over the Sinnoh Region, so try your luck.I'll give you a start - One Rare Candy is in the Old Chateau
You can find rare candies in mountains and you can use th dowsing machine.Rare candies can level up Pokemon,but beware,the Pokemon wont be as strong as the level is. It will get a bit stronger but not as strong as you think...:(
the rare candies are at the bilding befor national park inside go th the door on the left at the pokelethion when you enter you play games and earn points you need 2000 points for a rare candy
deleting all youre Pokemon but not youre starter then fly home