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X-rayXenonXeroxSince the question asked for "three-letter" words beginning with "X", how about "xis"?
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There are no German foods beginning with the letter X (Xereswein (sherry) is not really a food)For a list of German words beginning with X, please see the related question.
No country begins with the letter X.
There are countries that begin with letters A-W and Y-Z. However, there are no countries in the world beginning with X.