He used this special techinque i think from jiraiya or somebody else , and killed him. But he felt sorry since Naruto later on mention that jiraiya cared for him long time ago since he was his pupil and he wrote a book about pain. Pain realizes that and used a very rare special technique to bring injured people back to normal (heal people that is injured) but not those who are dead. Pain is more like NAruto. the girl is like sakura and the other boy is like sasuke, well sort of...
..............what other boy and by the girl do not you mean konan?? but which boy is it zetsu or .,.......who???
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because he was about to figure out who the akatsuki a.k.a the real pein was and pein did not want anyone to kno so he kil him and also because jiraiya knew about the jinchuuriki and stuff and pein wanted it but jiraiya refused to say anyfin and the started fighting then jiraiya lost which lead him to death but anyway i think it was something to do about the jinchuuriki and the little group that pein has and there true identity and also about the real pein
Yes pain killed him
Jiraiya fights Pain/Pein from episodes 126-133 BUT IF YOU WANT JUST THE FIGHT WITHOUT THE INTRO WATCH EPISODES (watch 129 if u want to watch konan fight too) 130-133
Konan appears in the episode Jiraiya infiltrates in the Village of pain, but Jiraiya defeats her easily, she makes many apereances near pain in other chapters to come, but she isn't really an important character
It is chapter 382 in the manga, and episode 133 in the anime. The Anime title is called The Tale of Jiraiya the Gallant and the manga is real choice!! or my decision. Jiraiya was stabbed in the back by the six paths of Pain and lost his throat and arm in the process, but believed Naruto as the child of prophecy and passed on the knowledge of Pain and the memories of himself to Naruto as he sunk to the bottom of the ocean and took one of the six paths of Pain out before his official death
Naruto kills all the six pains but nagato who controlled them died while reviving all those whom he had killedAll the pains were killed by naruto but nagato who controlled all the pains gave his life to revive all the people he killed