Katniss wants to split from the alliance because she eventually later on when all the other tributes are dead she and Peeta will have to kill all the tribute they made alliances with.So in my opinion that is a good idea.
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Yes, she does. They form an alliance in Catching Fire, along with Finnick, Peeta, Nuts, and Volts. Nuts and Volts are what Johanna call Beetee and Wiress.
Katniss Everdeen puts her name in multiple times in the reaping in exchange for food in Catching Fire. This act is called tesserae in The Hunger Games series.
Peeta and Katniss.Catching Fire revolves around Katniss's fake pregnancy with Peeta's child and their marriage. There is small Katniss/Gale mentioned, such as Gale's quick kiss with Katniss, but the main pairing is Katniss/Peeta.
Katniss Was Passed Out And Peeta was still in the arena
Romulus Thread, the new head peacekeeper.