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Luffy defeats Doflamingo with his near 'Gear 4' techniques. Gear 4 blows air into his muscles, and hardens his skin with haki, without making it any less elastic. This let him deal incredibly powerful punches by contracting his arm into itself and letting it recoil. In the last blow of the fight, Luffy used a bit of Gear 3, inflating his compressed arm to giant size, smashing through Doflamingo's attacks and defences, and punching him straight through the bedrock into the underground port.

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Q: Who will win between the fight of Luffy and Doflamingo in One Piece?
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