The fight between Luffy and Crocodile starts from episode 122
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There is no such episode. You might be thinking of episode 101 of the original series; Gotta See! Gotta Know! Kakashi-Sensei's True Face!
Season 3, Episode 3: Gridlock
This happens in season three.Episodes are:Episode 71: An Unrivaled Match: Hokage Battle Royale!Episode 72: A Mistake from the Past: A Face Revealed!Episode 73: Forbidden Secret Technique: Reaper Death Seal!
Episode 90 You Can Watch It Naruto-tv.com
she sings in the face the music issue.