In the episode called 'Driven' (4x11)
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season 7 "in-laws and out-laws"
This is a very intense season, mainly for Tony and Ziva. Ziva is very mysterious in this season, as she has many secrets. In the beginning there is a mole at NCIS and it turns out to be the newly interned Agent Lee, who was later shot by Gibbs in a pivotal episode. At the beginning of the season we see that there is another man in the room with Ziva when she is talking to Gibbs. Throughout the season we also saw her go back to Israel and saw a picture (twice) of a mysterious man. At the end of the season, her loyalty to NCIS is tested due to her relationship with assassin boyfriend Michael Rivkin. When Tony finds out about her boyfriend he gets suspicious and after a confrontation and fight, kills Rivkin in self-defense. In the end, Ziva, Tony, Vance and Gibbs go to Israel to answer to Mossad for Rivkin's death. In a cliffhanger ending, Gibbs leaves Ziva in Israel after she asks him to choose between she and Tony. In a cliffhanger ending, we see Ziva being tortured and interrogated by Muslim terrorists.
Pretty sure it was just made up for that episode
They Don't. In the episode Under Covers Season 3 episode 6 it think, they are undercover married assassins and although they kiss it is acting. Although it is still a mystery what actually happened that night. The closest they actually got is in episode Reunion season 7 episode 2. Ziva kisses tony on the cheek but it is very romantic and cute Long live TIVA!
Cote de Pablo is not leaving the show NCIS, and will return for season 7! Her character, Ziva, however left left the organisation but not the show and returned to the Mossad, to carry out the mission of Michael Rivkin. Gibbs was given the ultimatum on the tarmac of the airport, but he chose Tony