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I believe George Washington is more famous because he developed our nation, Darth Vader betrayed his own son.
Mentioned in the movies: Darth Plagueis Darth Sidious (Senator/Chancellor Palpatine) Darth Maul Darth Tyranus (Count Dooku) Darth Vader (Anakin Skywalker) In the Expanded Universe (comics, novels, games, etc.), there are dozens more, e.g. Darth Bane, Mara Jade, Asajj Ventress, Darth Talon, Darth Sion, Darth Malak, Darth Revan, etc.
It could be argued both ways. But directly he did not. He convinced his father to come back to the good side. When he did Darth Vader killed the emperer. That caused Darth Vader to die because it was only through the emperer's power that he was being kept alive. He was injuring by lava in his fight against obi whan. So when he killed the emperer Darth Vader died. So technically nobody killed Darth Vader he just died. However it also could be argued Luke is to blame. If he had not convinced Darth Vader to come back to the light side of the force he would not have died.
Darth Vader
Lord (Darth) Sidious