it would take days so read the manga .i hate it
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Naruto vs. Haku, Naruto vs. Orochimaru, Naruto vs. Kimimaru, Naruto vs. Sasuke, Naruto vs. Deidara/Sasori, Naruto vs. Orochimaru, Naruto vs. Pain.
Chapters 430 to like 444. The way the chapters are im guessing that it how much is about Naruto vs. Pain.
In episodes 166-169
No Pain isnt. As it reveals in later episodes of Naruto Shippuden. The 4th Hokage is Narutos father. Come on they even look the same with the hair and stuff.
Amegakure aka Secret village of Rain