The NarutoxUT OVA, which was a collaboration project with Uniqlo, a popular Japanese clothing brand.
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I think you're mistaken for the OVA. If its for the last battle between Naruto and Sasuke then its the OVA. But if you're thinking of a movie then you might thinking of the first Naruto Shippuden movie with the prediction of Naruto dying.
This is a bit of a vague question, but I'm assuming that you are speaking of that "episode" where Sakura is holding Naruto's head by her lap with the incredibly cheesy 'oh-look-the-sun-is-coming-out scene? In that case, that is not an episode; it is an OVA (Original Video Animation; basically means the anime in a nutshell) that is about 5 minutes long. It is titled "Sage Naruto Vs. Sasuke," I do believe.
Who told you she is his girlfriend she don't have any love feelings about him and he don't have love feelings about Hinata and Sakura loves Sasuke and Naruto loves Sakura and Hinata loves Naruto.
No where. Naruto and Sakura never kiss.
Its when naruto, sakura, and sai go on their first mission.