1. Tsunade never killed Jiraiya.
2. The part on peeking was a flashback and was never introduced as an episode.
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lol the question says what episode does jiraiya and tsunade fight orochimaru, and its 52 not 133, 133 when naruto and sasuke fought
Jiraiya trains Naruto in many episodes. Jiraiya is Naruto's new trainer instead of Kakashi sensei. But Jiraiya starts training him in episode #53 and just becomes Naruto's new trainer, also, Jiraiya is one of the three legendary sannin along with Tsunade and Orochimaru.
because tsunade sent jiraiya on mission
I may be possible. Why? Because Masashi Kishimoto, the creator of Naruto, based Jiraiya, Tsunade, and Orochimaru off of a tale called The Tale of the Gallant Jiraiya. In that tale, the character Jiraiya is married to a woman called Tsunade. Orochimaru is Jiraiya's enemy, and attacks the couple. So, it may be possible that Jiraiya and Tsunade like each other in a maritial way.
I believe it was... Tanzaku town? that sounds about right... :)