Sting's Shape of My Heart was used in the movie Leon: The Professional. His guitarist Dominic Miller was involved with writing the song. Other singers including Craig David sampled it to make their own hit music.
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I know it was used in the 1980's movie A Night in Heaven
Waterboy.
Dirty Dancing, The Sandlot, Endless Summer
In the movie the dog breed was a St Bernard
You can't, the movie is fictional and was only used in Charmed.