There is no such episode because Prue and Paige never meet in the show.
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Phoebe, Paige, Prue and Piper
The oldest was Prue, followed by Piper, then Phoebe and Paige.
Prue, Piper and Phoebe's father's name is Victor Bennet. Paige's dad is Sam Wilder.
Prue full name Prudence Halliwell Piper Halliwell Phoebe Halliwell Paige Mathews
There isn't an episode where Prue & Cole kiss. Prue is basically repulsed by Cole & Cole & Phoebe are madly in love.