The first few episodes.
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the first time naruto and sasuke fight is in the third episode of season 5, ep. 107 The Battle Begins: Naruto vs. Sasuke.Then again from the end of season 5, ep. 128 A Cry on Deaf Ears through the beginning of season 6, ep. 134 The End of Tears. the following meeting between sasuke and naruto occurs at the end of season 2 of shippuden, ep. 51 Reunion, and a fight between the two ensues in ep. 52&53 The Power of the Uchiha and Title of season 2. in america, shippuden is in it's 10th season, so far naruto and sasuke have yet to cross paths again since the last time in season 2.hope that helps :)
Gaara V.S Sasuke happened in part 1 of Naruto. during the Chunin exams. episode 66 and 67 early in the series.
Naruto vs. Haku, Naruto vs. Orochimaru, Naruto vs. Kimimaru, Naruto vs. Sasuke, Naruto vs. Deidara/Sasori, Naruto vs. Orochimaru, Naruto vs. Pain.
Chapters 430 to like 444. The way the chapters are im guessing that it how much is about Naruto vs. Pain.
after the chunin exam To be a little more specific, Naruto encounters Gaara episode 77 Light vs. Dark: The Two Faces of Garra. They don't start fighting until, 78-80, naruto's Ninja Handbook.