It was season 3. "The Good, The bad And the Cursed". However, she was not shot directly. She was acctually just linked with another person named Bo.
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Marry go around
Phoebe from Charmed was married to Cole in the series.
He only tells Phoebe and Paige. Phoebe and Paige tell it to Piper. Leo finds out from Phoebe.
Phoebe and dex accidentally get married when billie casts a spell on the two of them but when dex finds out she's a witch their marriage is annulled. :(
There isn't an episode where Prue & Cole kiss. Prue is basically repulsed by Cole & Cole & Phoebe are madly in love.