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From Method to Madness
They met when she was looking for Chloe after she (Chloe) faked her own death. She found him in a cornfield after he came down with a bolt of lightning. She was originally planning to meet him anyway. She took him to the hospital and so on... Also, it happened first episode of Season 4.
episode 19
Episode 117
Actually, he does meet naruto in episode 12 and they battled in episode 14-15 or somewhere near that.